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There was a song in a musical about Marian the Librarian! So the first syllable is like a female horse. In Marion the first syllable has a short vowel, like the one in man and apple.(But I speak British English.)

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I would never expect Marian to sound like Marianne; I see and hear it as originally an adjective meaning 'something to do with Mary', where Mary can be the Tudor queen or the mother of Jesus. And Marion to me is a French equivalent of 'little Mary'. I prefer the look of Marian and the sound of Marion, but I would use Marianne long before either of the others.